Poly(3-Hydroxybutyrate)

    • Product Name: Poly(3-Hydroxybutyrate)
    • Chemical Name (IUPAC): Poly(3-hydroxybutanoic acid)
    • CAS No.: 26780-50-7
    • Chemical Formula: (C4H6O2)n
    • Form/Physical State: solid
    • Factroy Site: No. 36, Beisan East Road, Shihezi Development Zone, Xinjiang
    • Price Inquiry: sales2@liwei-chem.com
    • Manufacturer: Xinjiang Tianye (Group) Co., Ltd.
    • CONTACT NOW
    Specifications

    HS Code

    567686

    Chemicalname Poly(3-Hydroxybutyrate)
    Abbreviation PHB
    Casnumber 26780-50-7
    Chemicalformula (C4H6O2)n
    Appearance White to off-white solid
    Meltingpoint 175-180°C
    Density 1.25 g/cm3
    Biodegradability Biodegradable
    Tensilestrength 30-40 MPa
    Glasstransitiontemperature 5°C
    Solubility Insoluble in water; soluble in chloroform and chlorinated hydrocarbons
    Monomerunit 3-Hydroxybutyrate
    Productionmethod Microbial fermentation
    Refractiveindex 1.48

    As an accredited Poly(3-Hydroxybutyrate) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Poly(3-Hydroxybutyrate), 100g, is provided in a sealed, labeled HDPE bottle with tamper-evident cap for safe storage.
    Container Loading (20′ FCL) 20′ FCL contains Poly(3-Hydroxybutyrate) packed in 25 kg bags, totaling around 16 metric tons per container, moisture-protected.
    Shipping Poly(3-Hydroxybutyrate) is shipped in tightly sealed, chemical-resistant containers to prevent moisture absorption and contamination. Packages are clearly labeled with product identification and relevant safety information. Store and ship in a cool, dry, and well-ventilated area, away from direct sunlight and sources of ignition, in compliance with standard chemical transport regulations.
    Storage Poly(3-Hydroxybutyrate) (PHB) should be stored in a tightly sealed container, kept in a cool, dry, and well-ventilated place, away from moisture, heat, and direct sunlight. Avoid sources of ignition and incompatible materials, such as strong acids or bases. Proper storage helps maintain its physical properties and prevents degradation or microbial contamination. Always follow local regulations and safety guidelines.
    Shelf Life Poly(3-Hydroxybutyrate) typically has a shelf life of 1–2 years when stored in cool, dry, dark, and airtight conditions.
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    Certification & Compliance
    More Introduction

    Poly(3-Hydroxybutyrate): A Manufacturer’s Perspective on a Genuinely Practical Biopolymer

    Introduction: Real Shifts in Polymer Manufacturing

    Our journey with Poly(3-Hydroxybutyrate), often abbreviated as PHB, has followed years of responding to the demands of industries seeking a material that promises performance, sustainability, and cost efficiency. PHB stands out among biopolymers by offering a tangible answer to the environmental pressures facing plastics. We see requests for this material growing as customers recognize the growing need to cut reliance on fossil-based polymers. Unlike resins that require complex fossil processing or endless tweaking in the compounding shop, PHB, which we produce through fermentation of renewable resources, comes with a minimalistic input list and clear downstream benefits.

    Almost every week, we hear from organizations trying to balance regulations, consumer pressure, and actual processing needs at scale. Some come to us after a poor experience with so-called biodegradable replacements that don’t hold up under normal forming or product applications. In our production lines, every batch of PHB is built with these real-world demands in mind, not just for the lab, but for real use in bags, food packaging, or single-use items.

    Understanding PHB's Unique Profile

    PHB is part of the polyhydroxyalkanoates (PHA) family. Chemically, it contains repeating 3-hydroxybutyrate units. This structure gives PHB a biodegradable backbone, which is highly resistant to many solvents but sensitive to microbial digestion in composting and soil. Through our continual R&D, we have fine-tuned regular production models so that molded products offer mechanical strength similar to polypropylene, with a density close to 1.25 g/cm³. This can make transition processes from PP machinery more straightforward without extensive retooling.

    We commonly manufacture PHB in the form of resin pellets—uncolored, purely for universal use—leaving the door open for compounders and converters to add pigments or blend with other biopolymers for more tailored properties. In our hands, melt flow index clusters between 5-15 g/10 min (190°C/2.16kg), which suits most injection and extrusion lines. Tensile strength typically measures up to 40 MPa, and elongation hovers near 5-8%. These numbers have come from thousands of in-house and customer-monitored production lots.

    Applications: From Films to Rigid Goods

    The end-users who have adopted our PHB most successfully tend to focus on performance evidence, not just sustainability slogans. In food packaging, PHB demonstrates barrier properties that match, or occasionally surpass, many conventional plastics. We've seen food processors deploy PHB trays and wraps to cut landfill organic load, since the material doesn’t leave microplastics behind after composting. Rigid injection-molded items—cosmetic jars, spoons, seedling pots—show similar drop resistance to established plastics. Clients in Europe and Asia often replace short-cycle single-use package components, as PHB offers compostability certified by multiple agencies. Schools and hospitals have trailed utensils and serving items, reporting end-of-life ease and consistent hygiene standards.

    For film extrusion, our plant operators continually report smooth extrusion runs. Films in the range of 20 to 80 microns maintain clarity, flexibility, and a touch-feel that’s less squeaky than PLA or starch-plastic blends, which end-users often notice. Some customers even pair PHB films as laminates with other compostable films for multi-layer packaging that services both shelf stability and green marketing.

    We consistently see applications in agricultural mulch films benefiting from PHB's natural soil breakdown. Compared to PE films—which rarely fully degrade—PHB films plow under after a season, enriching the soil instead of polluting it. In medical sectors, PHB’s biocompatibility has found a place in slow-release devices and suture coatings. Our production experience allows us to control molecular weight closely, ensuring that the final goods deliver the desired release rates and compatibility.

    Comparing PHB to Traditional and New Biodegradable Plastics

    Years ago, our technical staff wore skepticism on their sleeves over bioplastics. Frequent issues plagued early “green” plastics: brittleness, processing headaches, and poor availability. Now, after years of pilot runs, field use, and real-world product launches, we’ve narrowed the key factors separating PHB from plastics like PLA, PBAT, or the older crop-based starch fillers.

    PLA (polylactic acid) often draws attention as a bioplastic leader. Yet in our plants, PLA runs tend to struggle under secondary heat exposures, with low softening points creating trouble in hot-fill packaging or even transport. PHB handles elevated temperatures better—glass transition around 4°C, melting near 175-180°C, matched by dimensional resilience that offers a closer substitute for traditional PP applications. Where PLA’s rigidity or brittleness falls short—think folded food containers or snapped utensils—PHB’s moderate elongation offers real-world durability.

    With respect to PBAT (polybutylene adipate terephthalate), which is often blended into biomaterials for greater flexibility and process stability, our technical teams note that PHB alone avoids the petroleum-based content found in PBAT. While PBAT definitely softens up blends, PHB stands apart for companies requiring a fossil-free, biosourced input while still achieving decent toughness for both film and rigid articles. Starch-blended polymers have their place for specific low-cost items but rarely reach the shelf life or packaging integrity achieved by single-polymer PHB. They also tend to attract moisture, causing warping and product breakdown before items even leave the warehouse.

    For those unfamiliar, mixing and compounding PHB does not require the plasticizers and stabilizers demanded by some other alternatives. Processors switching over from traditional plastics avoid hunting for obscure additives or hoping for consistent quality from agricultural feedstocks—our production lines keep input fermentation strains and nutrient supply stable, resulting in molecularly consistent resin from every lot.

    Environmental Impact: Beyond the Buzzwords

    From the ground up, producing PHB as a chemical manufacturer means wrestling every day with questions of carbon efficiency, energy costs, and water use. In moving to fermentation-based production of PHB, our operations have reduced fossil carbon input by over 70% compared to producing regular polypropylene. Since PHB can be composted in both industrial and home conditions under the right temperature and humidity, we see significantly lower end-of-life emissions. Tests with municipal composters and home gardens confirm that after a few months of exposure, the polymer leaves only trace biomass, with no microplastic residue.

    Our wastewater cycles in fermentation also prove easier to treat: the absence of heavy metals and persistent organic pollutants means we need less post-processing, with water recycling rates far higher than in solvent-heavy plastics manufacturing. We source feedstock from non-GMO sugar and starch crops, and the organic by-products often feed livestock or are converted to fertilizers, closing the loop in the agricultural chain.

    Challenges certainly persist. Price points for PHB remain higher than legacy plastics, due mostly to feedstock and fermentation process costs. As production scales and technology improves, these figures keep moving in the right direction. Already, we have seen that regulatory incentives accelerate market demand, enabling scaling and lowering costs per kilogram.

    Production and Quality Assurance: Day-to-Day Realities

    No one working in a chemical plant expects smooth sailing every shift. Bringing PHB to market in real volumes means dealing with batch variability, fermentation upsets, and downstream purification challenges. Our plant engineers have spent years optimizing agitation speed, temperature controls, and nutrient supply to keep microbial cultures thriving and waste minimized. Detailed monitoring keeps physical properties—such as molecular weight, crystallinity, and melting range—locked in from batch to batch.

    Each bag of PHB that leaves our warehouse has a full certificate of analysis with traceable data on melt flow, tensile strength, moisture content, and heavy metal residue results. This traceability has become vital for our customers—especially those in regulated packaging for food, pharma, and medical device applications. We have invested heavily in in-line NIR monitoring and frequent batch release testing, not only for compliance but because inconsistent product means wasted time for us and wasted orders for users.

    Long-term, our day-to-day focus is shifting from “can we make PHB?” to “how do we deliver it consistently and at scale?” Internally, we run ongoing pilot lines testing new fermentation strains, optimizing reactor geometry, and experimenting with continuous production over batch fermentation to limit fluctuations. This practical experience sets apart a manufacturer’s approach: unexpected issues like temperature spikes, nutrient variations, or downstream biomass buildup have forced process-over-process refinement. The practical outcome shows up in consistent, high-grade resin that converters can depend on through yearly production cycles.

    Customer Experience: Lessons From Field Applications

    Every application teaches new lessons. A few years back, a client in the catering industry trialed our PHB-based cutlery at mass events. Field data showed early trouble when product sat in humid warehouses—the tines warped and edges dulled before use. That failure wasn’t an endpoint; instead, our technical and QA teams traced the problem to excess residual moisture in the pellets. We adopted stricter drying protocols and implemented new moisture barrier bagging, resolving the issue through production learning, not simply product swapping.

    Another frequent question from packaging companies centers on colorability. Additive masterbatches work well with PHB—better than with PLA—allowing brand colors without process complications. This has encouraged several clients to scale from test runs to full consumer product launches. Others have raised concerns about shelf life for food-contact films. Experience shows that properly conditioned PHB retains freshness and clarity for months, rivaling traditional plastics, so long as storage stays below 35°C and moisture content stays under control. Routine monitoring catches any rare lapses early in the supply chain.

    Increasingly, inquiries come from converters aiming for compostable certifications in global markets. Independent labs working with our QA team regularly run compostability trials. Thanks to our tight control over heavy metals and polymer additives, PHB consistently clears regulatory hurdles in Europe, North America, and Asia. In regions with growing regulation against single-use or landfill plastics, PHB provides an answer for responsible brand owners trying to hit both compliance and sustainability targets.

    Technical Barriers and Ongoing Innovation

    It would be misleading to claim PHB is a straightforward drop-in for every scenario. While PHB holds up well under regular temperatures, its narrow thermal processing window can still trip up unprepared operators. Too much heat leads to rapid degradation and off-gassing, so we work closely with partners during scale-up to optimize barrel temperatures, screw speed, and back pressure in both injection and extrusion lines. Technical documents and hands-on trials help developers move past the steepest learning curves.

    PHB’s crystallinity provides mechanical strength but can make rapid cooling lines struggle with part warpage. Our R&D group, many of whom spent years in traditional plastics, now experiment with nucleating agents to alter crystal growth and improve part stability, especially for thick-section items. Each innovation—the result of actual shop-floor challenges—feeds back into production batches and new grades offered to specific segments.

    On a broader scale, fermentation process improvements—like using engineered strains that boost yield per glucose input—continue to push production closer to oil-based plastics’ efficiency. This combination of shop-floor learning, process testing, and customer feedback creates a product that isn’t stuck in theoretical application, but improved by every partnership and field use report.

    Market Trends and Global Context

    Market conditions compel us to keep our eyes on more than just the production floor. Demand for compostable plastics continues to rise, driven in part by consumer activism and regulatory bans. Companies that years ago dismissed green plastics now ask about PHB for mainstream packaging conversions. Large-scale brand owners search not only for “green” credentials, but for real improvements in supply chain transparency and predictable product quality.

    Working through multiple market cycles, we have seen how spot shortages and price spikes for petroleum feedstocks send ripple effects through user segments hungry for more reliable sources. PHB offers a solution grounded in renewable resources, diversifying away from fossil bottlenecks. As synthetic biology and factory automation mature, biopolymer production lines achieve greater stability and less exposure to the price swings that plagued early green plastics.

    Traditional petrochemical giants and new market entrants now begin investing heavily in biopolymer facilities. As operating experience grows, so do the economies of scale, and what started as niche pilot projects become everyday features in packaging, food service, and even automotive trim components. Some of our newest inquiries arise not from sustainability pressures, but from specifiers seeking advanced performance characteristics—heat resistance, biocompatibility, low odor, and clean end-of-life breakdown.

    PHB continues to draw attention from companies looking to future-proof their product portfolios. Many of our customers are transitioning from trial orders to full production runs, showing that faith in PHB is not just philosophical, but grounded in demonstrated manufacturing outcomes and clear product performance.

    Partnership and Shared Progress

    The success of PHB in the marketplace stems less from slogans and more from close partnerships between producer and user. Every advancement we make in material consistency, processability, and sustainability comes from open troubleshooting and an honest sharing of field failures as much as successes.

    By investing alongside our partners in downstream compounding, packaging, and logistics know-how, we avoid the pitfalls of many new materials that fade due to over-promising and underperforming. Each new application feeds learning back into plant operations, R&D, and quality teams. Many converters now anticipate PHB’s slightly different feel or process window and adjust equipment and designs accordingly rather than expecting a one-to-one swap with legacy polymers.

    This back-and-forth, grounded in real batch data and day-to-day plant realities, has produced a product line that evolves with each production run and each market breakthrough. By sharing practical experience across the chain, both in successes and failures, PHB stands not as a flash-in-the-pan innovation, but as a robust and proven material ready to meet the next challenges facing plastics.

    Conclusion: PHB as a Living Material in Modern Manufacturing

    Manufacturing PHB at scale does far more than provide a certified biodegradable plastic. It compels us to rethink sourcing, processing, product design, and lifecycle management from start to finish. Each client application, technical hurdle, and regulatory update advances our understanding, making PHB not just a polymer formula, but a practical tool for companies balancing market demand, compliance, and real-world manufacturing constraints.

    We look at our journey with PHB not as a finished story, but as a continually evolving process shaped by every pound of material shipped, every test in a customer line, and every improvement coming off our fermentation and extruder lines. Real experience—built from success, failure, and collaboration—keeps PHB advancing as a foundation for high-performing, sustainable plastic goods worldwide.